Product ID:O-S-801 CLASS 3
MSDS Date:01/01/1985
FSC:6810
NIIN:00-249-9354
MSDS Number: BDNSG

ALLIED CHEMICAL CORP

COLUMBIA RD AND PARK AVE
MORRISTOWN, NJ 07960
US

Cage: 1L168

ALLIED-SIGNAL INC

1087R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 37.5%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Effects of Overexposure:IRRITATION AND BURNS TO THE SKIN, EYES, NOSE,
AND RESPIRATORY TRACT. PULMONARY EDEMA, BRONCHIAL EMPHYSEMA,
CONJUNCTIVITIS, STOMATITIS, DENTAL EROSION.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR.
IF BREATHING IS DIFFICULT GIVE OXYGEN. EYES: IMMEDIATELY FLUSH WITH
PLENTY OF WATER. SKIN: WASH WITH SOAP AND WATER. REMOVE
CONTAMINATED CLO THING AND SHOES. INGESTION: DO NOT INDUCE
VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. GET MEDICAL ATTENTION.

Extinguishing Media:FOR COMBUSTIBLES, USE SUITABLE DRY CHEMICAL. NO
WATER ON ACID.
Fire Fighting Procedures:GAS MASK WITH SULFURIC ACID ABSORBING CANISTER
APPROVED BY THE BUREAU OF MINES.
Unusual Fire/Explosion Hazard:REACTS WITH STEEL AND MANY COMMON METALS
TO PRODUCE HYDROGEN GAS WHICH CAN BE A FIRE AND EXPLOSION.

Spill Release Procedures:COVER WITH SODIUM CARBONATE OR AN EQUAL
MIXTURE OF SODA ASH AND SLAKED LIME. AFTER MIXING ADD WATER IF
NECESSARY TO FORM A SLURRY. SODA ASH AND LIMESTONE WILL RELEASE
CARBON DIOXIDE GAS REQUIRING ADEQ UATE VENTILATION.
Neutralizing Agent:SODA ASH OR LIMESTONE

Handling and Storage Precautions:SMOKING, OPEN LIGHTS, AND SPARKS NOT
PERMITTED IN STORAGE AREAS. PROTECT CONTAINERS AGAINST PHYSICAL
DAMAGE AND PREVENT CONTACT WITH WATER.
Other Precautions:SEPARATE FROM CARBIDES, CHLORATES, FULMINATES,
NITRATES, PICRATES, POWDERED METALS, AND COMBUSTIBLES. WEAR RUBBER
GLOVES, CHEMICAL GOGGLES, RUBBER BOOTS, AND CHEMICAL A CARTRIDGE
RESPIRATOR.

Respiratory Protection:INDUSTRIAL CANISTER TYPE GAS MASK APPROVED BY
U.S. BUREAU OF MINES
Ventilation:AS REQUIRED TO REMOVE ANY MISTS OF TOXIC GASES
Protective Gloves:RUBBER
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:RUBBER APRONS, RUBBER SAFETY SHOES, FACE
SHIELD, CLOTHING
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SULFURIC ACID OXIDIZES, DEHYDRATES, OR SULFONATES MOST-ORGANIC
COMPOUNDS. EXCESSIVE HEAT IS GENERATED WHEN MIXED WITH WATER. AVOID
CONTACT WITH SULFIDES WHICH MAY EVOLVE TOXIC FLAMMABLE HYDROGEN
SULFI DE GAS.

HCC:C1
Boiling Pt:B.P. Text:230F,110C
Vapor Pres:0
Spec Gravity:1.84
Evaporation Rate & Reference:< 1 (BUTYL ACETATE = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS, OILY LIQUID WITHOUT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CARBIDES, CHLORATES, FULMINATES, NITRATES, PICRATES, POWDERED METALS
Stability Condition to Avoid:HEAT, HUMID AREAS
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN SULFIDE,
HYDROGEN GAS

Waste Disposal Methods:NEUTRALIZE ACID WITH LARGE AMOUNT OF WATER, SODA
ASH, AND SLAKED LIME BY STIRRING. DISPOSE OF BY STORING IN APPROVED
STORAGE CONTAINERS FOR CORROSIVE LIQUIDS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.